What’s the best or recommended way to test out Plasma 6 RC2?
Neon Testing in a VM (or on bare metal if you're adventurous). Arch with the kde-unstable repo is good too, but that also includes a snapshot of the unreleased Qt 6.7 which introduces more bugs.
What has been the hardest problem to solve moving to Qt6?
Personally I'd have to say the large number of API and behavior changes in QtQuick that Qt 6 has brought. We use QtQuick very heavily throughout KDE, so this has required a lot of mandatory porting work, more than in our QtWidgets-based software. And there have even been changes between Qt 6.5, 6.6, and 6.7, so it's still a bit of a moving target
In addition to the obvious answer of "because our software is really good!", IMO an under-appreciated reason is that KDE truly is an anarchic and largely volunteer-run community. As long as there are passionate volunteers, there will be KDE; you don't have to worry about it just dying one day should some big corporation pull the plug for some reason. We've all become so accustomed these days to software being disposable, but KDE really does give you a measure of longevity and continuity that you're unlikely to get elsewhere, especially without paying a lot of money for it.