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Community Guidelines
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Pretty sure chloroform is wrong too.
Chem teacher had some and one kid stupidly took a whiff. She dropped like a sack of potatoes. She woke up in a few seconds but yeah - that shit was instant.
I guess it might take 5 minutes to get enough to be out for a few hours.
Here's what I can find that gives a better answer. Above 100ppm, you'll rapidly start feeling dizzy. But chloroform is also highly volatile, so you would need to have a rag soaked in chloroform just before attacking someone, rather than lying in wait for a few minutes to a few hours. Plus, if you get that concentration too high, you can accidentally kill someone.
So if you'd been hiding in someone's car for 10 minutes, that rag might have lost enough efficacy that it would take a few minutes. Alternatively, if the person in the backseat doused the rag just before attacking the driver, it might be nearly instant.