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Of course fentanyl cannot be absorbed through the skin. Remember when the Merry Pranksters were planning to combine LSD with another drug that could be absorbed and paint the drinking fountains of the Republican National Convention? They didn't, but those were the days,
I'm assuming you're talking about handling a dry powder form, to which I have zero experience so I can't comment on. BUT fentanyl is absolutely administered through the skin with patches, used for slow release pain control. They're incredibly helpful for people who aren't getting medicated regularly or have difficulty with oral medications.
There are formulations that can be absorbed through the skin -- transdermal patches for fentanyl exist -- but it is certainly not going to happen accidentally or with regular formulations.
Doesn't need to be absorbed by the skin.
Opening it and having trace on your hands can land some of it in your mouth, eyes, nose, etc.
Don't know if it would be enough to do harm, but pure fentanyl can kill at 2 milligrams. Which you could get in you through simple trace.