Probably any distro that ships KDE Plasma 5 as default - I'm stuck with GNOME for now as I need to use Evolution for work (EWS mail accounts), but if I had the choice I'd probably be on Plasma.
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It's hard to use anything else once you've configured plasma to do the exact things you want.
I probably switch what I'm using every few months. The thing I cannot live without though is tiling support, whether just inherent to the window manager I'm using or an extension, I find it painful to use a computer for anything serious without one now.
Currently using KDE with the Bismuth extension (Fedora Kinoite) which isn't perfect but not bad. I'm eyeing Hyprland up from afar but as an Nvidia user I have too many issues on Wayland at the moment.
I am into KDE Plasma, it works quite well on my distro (Fedora by the way) and one thing that I like about is is that I can make it truly mine. Defaults are nice, however sometimes I think I don't need that or need something else, and quite often I manage to do it to be the most comfortable for me. It's also very customisable and with enough learning you could rice it into quite a lot of stuff, even though I myself don't really know a lot how people do it.
For me, it's Fedora + KDE when I need a GUI. I used to be an AwesomeWM guy for a very long time but I needed a proper GUI for my 5 year old. I'll convert her to i3 or Awesome one day....
KDE and Ubuntu
Honestly Opensuse with gnome or kde is really amazing!
Currently using Fedora as my daily driver, stock GNOME + the "Dash to Dock" extension with the dock on the left is the perfect setup for me.
Any with MATE or Xfce as an option (which tbh is basically all major distros). I just use a specific theme to give me the glossy, frutiger aero look and I'm happy. Currently on EndeavourOS using MATE as my DE.
Just trying out OpenSuse microOS currently, as an alternative to Fedora Kinoite, and the installer doesnt even load.
I dont like Ubuntus variant of Gnome. I think GNOME can look good but its apps are often horrible. Mint has a better set of simple but powerful tools.
But I would stay with anything rocking KDE. I recommend fedora Kinoite fro ublue.it (better video previews and working RPM firefox basically), its a really great distro.
I'm happy just sitting on Debian 12 with KDE Plasma. I don't really consider any the "best", but it does what I need and has never bothered me.
My favorite while I was using it was Cinnamon due to its simplicity. In the future, it would probably be Budgie, as the pipeline of changes looks really promising and its just as simple as Cinnamon.
I'm an arch kde user, but I gotta say Elementary / pantheon is / was incredibly beautiful. They took a lot of the simplistic design principles from iOS, and made something even prettier.
Garuda is the first distro to really excite me visually since the KDE3 days. I just wished it booted faster.
When I switched over permanently at the release of proton, I went with Cinnamon since it was the most familiar to me. Before that I tried Ubuntu in the past.
After 2 years on Cinnamon I switched over to KDE Plasma since I want more tweakability and customization and Cinnamon and Gnome in general is just severely lacking in that regard.
And it was a good choice as well since KDE has a lot of options to tweak and I can make it look how I want. I also love fluid animations and KDE has that in spades together with early and now very stable Wayland support.
I could not be happier and I don't see any reason to ever switch to another GUI.
Currently I am using Cinnamon with Debian and quite like it. Previouly I enjoyed XFCE, espacially on slower laptops. Never really liked GNOME or KDE Plasma though. GNOME has too many animations and feels slow. At the same time its not very customizable. KDE on the other hand feels slow as well and though it is kind of fancy it seems not to be my taste and I did not like the way you customize either. That is not so important to me anymore. So please don't read from this that Cinnamon or XFCE would be great for customization. I would not know it.
For some reason I find stock GNOME UIs appealing
The last “beautiful” out the box distro I tried was a small one based on arch called XeroLinux that was just a customised KDE Plasma.
I run tiny core linux for the UI personally
I fell in love with xubuntu ten years ago. I wouldn't change it for anything.
I love me some good old MATE desktop. Especially with how Linux Mint customizes it, it's pretty good
If best GUI means configurable and pretty, I have not yet found an alternative that can compete with good old Xfce. It is the only modern desktop environment for which I can still modify the theme of the window decorations to my liking. It is fast and stays out of the way. Using it both on Ubuntu and MX Linux, both based on Debian.