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This can be done, it's called nuclear fusion and the sun does it constantly. The practical limitation is, largely, overcoming the electrostatic force.
Basically, because the atoms are similarly charged, squeezing them together is like trying to push together the North sides of two magnets: they repel each other. It takes a massive amount of energy to squeeze them together hard enough to overcome that repulsion, fortunately the sun has enough energy to do this fairly easily. It is much more difficult for humans to do.
So does the sun just have huge amounts of helium? Where is it getting all that helium? Can we have some
It's making it, from the tons of hydrogen it has in the fusion process. The energy and the reason stars even do this is because all of that mass that close together spontaneously does that; starts fusing.
We can't have any, because a star will use up all the hydrogen to make helium, then start using all of the helium to make carbon and oxygen. Then start to make...
This is overly simplified and it varies from star to star (the more massive the star, the longer it churns through "making" elements into more "complex" elements) until its core is all iron, at which point fusion becomes a net negative.
From there other things can happen like novae. All throughout this life process though, that "elemental conversion" is happening faster on the outside as opposed to the core, and stellar winds do blow off heavier elements that enrich the interstellar medium.
We need a shovel that can plunge into the sun's core if we want its helium, TL;DR.
Our sun will stop at carbon, then hang around until it either becomes a brown dwarf, or flies through enough matter to his the Chandrasekhar limit, then KABOOM!
That would be cool to watch
You want to know what would have been really cool to watch?